Apologies, i was in a hurry. It has no cleavage it is simply broken on a flat surface. As it has no conchoidal cleavage it is safe to assume it is chalcedony, opal would show conchoidal to uneven fracture. The rock is clearly silica rich, you can even make out a small quartz geoid in the bottom left corner of the picture.
I assume we might be counting the numbers in a different order?
Middle row, to the left. It definitely has cleavage.
As a side note: Chalcedony does also show conchoidal fracture (not cleavage!).