I would agree that's slag... and also agree that Virginia does have obsidian.
The state has two ‘young’ volcanoes in the Appalachian Mountains: at Mole Hill and at Trimble Knob. The sources exist today as the heavily-eroded necks and remnants of the interior of primeval volcanoes. They do nevertheless have the remains of gaseous vents within which there is still unweathered obsidian, first identified and documented by geologists in 1899. A few of the obsidian artefacts found in Virginia have definitively been attributed to these sources, so ancient people must have discovered them. Also, the Smith and Dan Rivers that originate from the Blue Ridge and Appalachian Mountains carry occasional pieces of obsidian from these sources into the Piedmont along the NC/VA border and that’s where many of the obsidian artefacts have been found., typically dating between 2,000 – 10,000 BC, which is well before the believed lithic trading networks existed.