When you heat treat stone it binds the silica together so it can be flaked easier , some agates will change colors, the brown chert in my area will turn red to a small depth of the stone. A lot of stone has a dull luster to before heating and after it will have a gloss shine. Novaculite from Arkansas comes in all colors it always has a gloss after heating, if it is gray it turns white, if it is translucent it may go pinkish or get clearer, black stays black but has a high gloss to it. I don't really know of a set time period on heat treating, someone else may know for sure. Most native people would dig a pit a few feet deep, layer the bottom in sand 6in or so thick, place the stone they wanted to treat, then cover them with more sand 6in or so then cover with dirt and build a fire for a day or little longer, then let it cool down.