Cans will tone off of a much larger area of your coil than coins. In fact most cans will beep before the edge of your coil has crossed over them. So if you're getting a high tone under the entire area of or coil, it is probably something big. Or if you are getting a high tone that is difficult to center over before you pinpoint, it is usually something large, like a can. Coins are pretty tight under the coil, especially if they are under ~4 inches or deeper.
Also, 50-tone makes it much easier to distinguish cans, IMO, as they sound wonky or lopsided. But I still much prefer 5-tone at this point for what I do.
Either way, more time with the machine will get you the skill to distinguish.