First off I would like to say, DO NOT scratch things with a pocket knife or acid test them in stores where they are being sold. Also worth noting, don't scratch things with a random piece of metal you found which is copper or something because odds it transfers and you will think the new item is copper also. Instead why not use your noggin and just check for wear areas instead of damaging things (your eyes are your best tool), or pay the minimal price if you think it is worth the risk. This trick could be useful if metal detecting, scrapping, pulling stuff out for free, but trust me I have seen it happen, if you are caught scratching an item being sold at a thrift shop, antique mall, flea market, etc... You will get any number of reactions or combination of them (also gives pickers a very bad rap):
1. You are told DO NOT do that again or else.
2. You are told you WILL buy the item now.
3. You will have the police called.
4. You will be asked to never come back again.
Magnet test is a good cursory check on things if you suspect them not being real in the jewelry counter. However, with a powerful magnet I have seen some gold/silver jewelry still slightly attract to the magnet, also if there is a spring inside the clasp, odds are it will be attracted to a magnet. Also is jewelry that is partial junk and partially not. Also just because it doesn't stick to a magnet does not mean it is precious, there a are lot of junk metals out there that jewelry and other things are made of. Go test some pots in the pot area, or a lot of the blatant costume jewelry.