The IgnitionPIN website is correct in saying Pinfire cartridges became obsolete in the 1860s, when Rimfire (and shortly afterward, Centerfire) cartridges became the preferred version of bullet cartridges. However, because people still owned many-many thousands of Pinfire-ignition firearms, large quantities of Pinfire cartridges continued to be manufactured for several decades after the 1860s. As the IgnitionPIN website says on its 12mm-cartridges webpage, "They have been obsolete since the early-1900s."
12mmPinfireRifle
So, DigginDownUnder, the only way the 12mm Pinfire cartridges you found can be accurately dated is if they have a maker's-mark stamped on their base. The link given to you by Calisdad (
IgnitionPIN) has some info about that.
Also, because you are digging in Australia, you'll need Pinfire maker's-mark info from the four countries which manufactured "most" of the Pinfire cartridges (France, Britain, Germany, and the US). Here's a link about a US-made 12mm Pinfire cartridge with a very unusual maker's-mark (with photos):
THE CARTRIDGE COLLECTOR
Here is time-dating info (with photos) about one of the French manufacturers of pinfire cartridges, Fabrique Gevelot. Note, there are several variations of that company's marking, which date from 1832 through the 1880s. Scroll down to almost the end of the webpage.
THE CARTRIDGE COLLECTOR
Here's some info (and photos) about an 1880s/90s German maker-marked pinfire cartridge. Again, scroll down to almost the end of the webpage.
THE CARTRIDGE COLLECTOR