As for chalcedony vs carbonate he should take an iron nail and see if it scratches the rock at some point, press hard Kjane.
When it comes to the yellow stuff which I was referring to, I don't think it is gypsum. Kjane mentioned in a post above that it is a hard material and gypsum is only 2 on the hardness. That aside, you can see in a second to last picture he posted when you zoom in, that it is made of small elongated interlocking crystals. That form is more common in zeolites than anything else. Something similar in form is to be seen in dolomite and ankerite crystals.
If that is the case he should be able to scratch the crystals to whit a nail. But that would not exclude zeolites as most zeolites can be scratched with a nail. The only way to know with some certainty is for Kjane to do an acid test, so if you Kjanu don't have any acid with you, maybe you have some vinegar? Try to warm it up a little if you have any before you spill a little over the minerals to see if they fizzle.
The yellow coloration is highly unusual and it resembles more road paint than anything else. The pictures are to blurry to tell anything for sure.