Nice Old finds, you can find similar examples of your buckle here,
dates ranging from 16th to 20th century: http://www.ukdfd.co.uk/ukdfddata/showcat.php?cat=176
Chain needs closer exam for me to know.
HH to You!
On wrought chain, it has to be clean enough so you can see the forge welds. They'll be irregular diagonal hairlines. Modern welds are a ring, but they were removed on older/better chain.