In the photo they appear to have a raised-lettering backmark, which on dug-in-the-US brass (or copepr) 1-piece flatbuttons means manufacture between about 1790 into the late-1830s. On buttons from that time-period, the word "gilt" meant gold plating, and the word "plated" meant silver plating. Your buttons are made of the legendary British Sheffield Silverplate, a thin layer of sterling silver bonded onto a layer of copper.
You asked for their value. Dollar-value of ones with no silver remaining is about $1... at least, that's what you can buy "dug" (excavated) ones for at relic-shows here in Virginia. Dug flatbuttons with "a lot" of silver still showing and looking pretty can bring $5 to $10.
You asked about how to know if you've found a Tombac buttons. Tombac is an alloy of about 85% copper and 15% zinc. (That's less zinc than is typically found in yellow brass.) Consequently, actual Tombac is an "orange-ish" or "golden" color. Some modern-era Canadian 5-cent coins were made of Tombac. See the photo below.)
What most diggers call a Tombac button is actually made of "White Tombac"... which has a dull silvery looking color. It is the usual copper-&-zinc Tombac alloy except that it also contains a small amount of the metallic element Arsenic, which has the effect of turning the alloy to a silvery-ish color. Perhaps the presence of a trace of Arsenic is why (White) Tombac buttons tend to come out of the ground looking nearly as clean and shiny as the day the were lost.