That type was very commonly used on the "fly" of pants before zippers were invented, and also on long-john underwear. (And probably other articles of clothing). Because it is a thick cast brass disc rather than inexpensive stamped-sheetbrass, I think it is "probably" from more than a few decades before the civil war. If I recall correctly, the first of the much-cheaper-to-manufacture stamped sheetbrass 4-hole buttons was patented in Britain in the 1830s.