i have a book that says you can use nitric acid to test for silver.here are some of the particulars; nitric acid test kits can be obtained from jewelry supply houses.before handling any acids be sure to follow the following safety rules
-do not inhale the fumes
-keep the bottle tightly capped when not in use
-nitric acid has long been the chief chemical for testing precious metals. it is volatile and should be handled with extreme care and caution.as the name denotes, it is acid
-acid will seriously burn your skin
-a drop in the eye will make you blind WEAR A FACE SHIELD AND GOGGLES!
-always wear long sleeves and heavy gloves while using nitric acid
-do not use rubber gloves
- do not use rubber gloves because this acid can and will burn through them very rapidly. heavy canvas or heavy leather gloves are best.
-do not attempt to store a large quantity of nitric acid in your home.it presents an extreme hazard to persons in case of a fire or other accident
-use in a well ventilated area
-do not use near fire or flames
-do not smoke while using it.-always use a glass dipper rod attached to the bottle cap
-do not use brushes as they can cause tiny droplets to fly about
-read and re-read all safety instructions
that being said here is what the book says about using nitric acid to test silver.
a notch is filed in an inconspicuous place,if possible.the notch is filed because of the possibility of plating ....(not in your case!).... the notch only need to be 1/32 of an inch deep. a drop of nitric acid is then placed in the file mark.if the item is made of high grade silver such as sterling,the acids will merely turn a grayish color.in other words,it will tone down the metal a bit,but will not change its basic color.
should there be a high proportion of copper alloying, a green color will appear. whenever green is obtained, you are dealing with either a low grade silver or an article made chiefly of copper with the addition of enough nickel or other metal to give the appearance of silver. this is usually accomplished by using 75% copper and 25% nickel.
be sure to remove the acid as soon as the test is complete. if this is not done, it can cause pitting and permanent discoloration.
i believe this information is primarily intended for the testing of silver jewelry, so it may or may not work in this instance. there is another acid test you can do using dichromate acid but the acid is hard to obtain and the test is more complicated.it is supposed to be hazardous and it is not recommended, so i will omit that information. i hope some of this information is helpfull...........one other thing, a jeweler can perform this test for you for a price.