Grapeshot was for Naval use, consisting of nine 2-inch-or-larger balls to smash the mast and rigging of an enemy ship. (You don't need balls that large to kill a person.)
Grapeshot's land-use equivalent was called Canister. It typically contained 27 (or more) "smaller" balls, to mow down waves of enemy infantry. Canister was like shotgun-ammo for a cannon. Grapeshot is anti-ship ammo. So, actual Grapeshot would not have been used in Montana.
If you want to solidly identify your iron ball, you'll need to super-precisely measure its diameter (in hundredths-of-an-inch), and also weigh it on a Postal Shipping precision scale, in tenths-of-an-ounce. Then compare its exact diamter and weight with the data on the artillery-balls charts here:
www.civilwarartillery.com/shottables.htm
The "Shot Tables" data-charts at that website cover every size of artillery ball from the Revolutionary War through the Civil War (including Confederate ones).
If there's no EXACT match for your iron ball's precision-measured diameter and weight in those charts, your ball is not an artillery ball. Good luck to you. I hope for your sake that your find is an artillery ball. Those historical-data charts will tell you with certainty, yes or no.
If there's no match-up, your iron ball is most probably an ore-crusher "mill-ball" (used in the Mining-&-Stonemilling industry), as SgtSki metnioned. Lots of ore-mining has been done in Montana.