Bottlecap for scale. All I know is it's not iron, it's broken and has some white corrosion. Maybe aluminum or could it be pewter? I'm not quite familiar with pewter.
I've also got these two pieces of copper that go together, not sure what they go to?
The first one looks like a riveted button, a huge one, maybe through a piece of leather? And maybe a chunk of a lantern or old gas lamp for the other? I dunno