It looks to me to be from smelting copper?
There are a lot of small pieces of the green shiney rock/glass (slag?) in that area.
Also, the downed limbs and twigs of the area have soaked up a greenish tint. I think there is a high copper content in the soil.
From what I've read, Native Americans did not smelt copper, but early Europeans did.
None of my maps show anything in this area at all. Maybe there is a colonial copper mine nearby.