Flint, Chert, Agate, Jasper, Quartz, Obsidian, Glass and many other types of brittle materials break with a conchoidal fracture. They break that way when someone whacks them with a hammer, they break that way when they roll in a creek for a while, they break that way when animals step on them, they break that way when a flake is used as a knife or when a tool scrapes on hard bone.
It can be hard to tell in a picture, heck it can be hard to tell in hand sometimes.
That flaking on the original pieces here could be use wear, intentional flaking, or creek damage.