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nice ring!
Do you have a diamond tester ? The ring could be silver with diamond in it! I found
one!
Have you looked in the band for any markings? It looks to me like it could be very tarnished silver. I would try some baking soda paste to see if it lightens up at all. If it was brass it should turn more yellow rather than the lighter grey of silver. It's a beauty though regardless of metal.