For anyone interested, these were my original notes, compiled some years ago for use in an information centre on another forum where I am a moderator:
The terms “flint” and “chert” are used interchangeably these days, but there is a geological difference.
Both chert and flint are composed primarily of quartz in the form of microcrystalline or cryptocrystalline silica. Outside America, the term “flint” is usually reserved for material which has originated from chalk deposits (or marl – a carbonate-rich mudstone) and “chert” for material from limestone deposits, but they are essentially formed in the same way. Chert tends to contain a proportion of microfibrous quartz and – although still fine-grained - consequently has a less uniform structure.
Beyond that, there is a spectrum of possibilities for which the distinctions have no clear boundaries. As the microfibrous nature increases, the material would more likely be termed “chalcedony”. When the quartz is composed of silica with extremely high purity it’s sometimes called “silex”. Jasper is essentially an opaque form of chert coloured by iron oxide inclusions.
Formation
Most chalk was formed principally from tiny planktonic sea-critters called Coccolithophores (a form of green algae) which had tiny “plates” of calcium carbonate and this accumulated in sea-bed layers over millions of years. Limestone more usually formed from the degraded calcium carbonate skeletons of corals and the tiny “shells” of Foraminifera (amoeboid protists). In both cases, that was also supplemented by partly decomposed molluscs and other organisms with a calcium carbonate structure. Within those layers there were also the skeletal remnants of vast numbers of simple sponges, composed of tiny needle-like spicules of silica.
When the sediments accumulated sufficient depth and became buried by enough subsequent material to create high pressures (and also high temperatures) the calcium carbonate compacted to chalk (or eventually limestone) and the silica dissolved. The dissolved gelatinous silica solution accumulated by replacement, filling any cavities in the chalk – such as burrows made by crustacea or burrowing marine organisms and voids left behind by decaying organic debris. Later, it also seeped into the zones representing the major bedding planes of the chalk arising from climatic change and geologic history.
A subsequent change in chemical conditions was the trigger for the silica to recrystallize in solid form and that’s what ultimately became flint (or chert). Those chemical changes may have arisen from the decomposition of organic material and/or diagenesis in the rock itself. Frequently some organic debris acted as a nucleus and the silica accumulated gradually by accretion. Flints sometimes contain a white or cream coloured soft powdery chalk deposit known as “flint meal” and this frequently contains remnant Echinoids and other marine fossils.
The re-deposition is seen mostly in the bedding plane layers of chalk or limestone. When it’s a continuous layer we normally call it “tabular” and when it’s in the form of scattered nodules or lenses we call it “nodular” but those nodules still normally represent a bedding plane and are not as randomly distributed as may appear to be the case.
The preservation of uncompressed fossils such as Echinoids and Ammonites in flint indicates that the replacement commenced early in the lithification of the chalk. The presence of flint sheets along joints and faults shows that the quartz remained mobile and recrystallised during subsequent burial, folding and faulting. Flint or chert beds (whether tabular or nodular) closely parallel the bedding planes in the chalk or limestone respectively.
Terminology
For early Europeans, the differentiation between flint and chert embraced a difference in quality, which is in turn a reflection of their geological formation. Flint was regarded as higher quality and that’s a function of it being formed in chalk deposits with a particular geological formation history, having a particular water content associated with dissolved silica originating from the sponge spicules. When Europeans arrived in the New World, the distinction based on quality was reinforced by the term “flint” being adopted to also distinguish between differing qualities of local chert. There was also a tendency to use the term “flint” to describe nodular chert (as opposed to chert in massive layers or beds), which also generally reflected that same quality difference.
It helps if you remind yourself that terms like flint, chert and jasper are not strict geological terms and certainly are no longer used as such with any universal agreement on form and composition. The popular use of the terms in a non-geological sense has been influenced more by the users of the materials and archaeologists than by geologists. As a general rule, geologists primarily classify rocks according to what they are – not how they formed – and may further qualify those terms with descriptions concerning formation.
Other than that, flint as it is generally geologically defined comes from European importation [with the exception of Georgetown Blue from Texas]. Flint cobbles were frequently used as ballast in empty ships arriving to take cargoes of tobacco, cotton and such. That material was often re-utilised for construction purposes and there are quayside roads in ports like Savannah, Georgia composed entirely of English flint.