More on flux's and their purpose.
Borax – comes in both hydrous and anhydrous forms and the latter is
recommended as the former must lose its water of crystallisation and therefore
tends to cause greater heat losses. Borax fuses at the relatively low melting point
of 742 o C, this appreciably lowers the fusion point of all slags and it also acts as an
excellent solvent for base metal oxides. The rational formula Na 2 O.2B 2 O 3 indicates
an excess of acid and dissolves and fluxes practically all metal oxides, both acid and
base. Borax also exhibits good fluidity in the molten state.
Silica – with a melting point of 1750 o C is the strongest acid reagent available. It
combines readily with metal oxides to form silicates. The main problem with silica
based slags is that they are very viscous and hence hold metal shot in suspension,
however when fluxed with borax, borosilicates are formed. These slags still exhibit
a high solubility for base metal oxides while affording control of fluidity. For further
reference material on borosilicate and silicate ratios, any assaying text should be
helpful.
Soda Ash – which melts at 825 o C is a powerful basic flux and is by far one of the
cheapest available. Owing to the ease with which alkaline sulphides and sulphates
are formed it acts as a desulphurising and oxidizing agent and possesses a very
high fluidity. Care must be taken when using soda as a fluxing agent as an excess
will yield a very sticky and hygroscopic slag which is difficult to clean from the
ingot. Also a strong soda based slag reacts exothermically with water and contact
with skin can result in severe irritation.
Nitre- or potassium nitrate is a powerful oxidising agent which melts at 339 o C. It
fuses at low temperature without alteration but at higher temperatures 500-600 o C
breaks up giving off oxygen which oxidises sulphur and many metals, notably lead,
iron and copper. A word of warning when using nitre is to control the amount
required as liberation of oxygen is a vigorous reaction and apart from overflowing
the crucible, will cause excessive crucible erosion. Nitre reacts with graphite
according to this reaction
4 KNO 3 + 5C →2 K 2 CO 3 + 3CO 2 + 2N 2
Charcoal- is used where a reducing atmosphere is required over a charge. As a
general fluxing agent for the treatment of concentrates it would find very little use.
However it is included in the flux list because of its obvious reducing capabilities.
Carbon does not become active until a temperature of 500-600 o C but can be used
effectively on a high copper content bullion to reduce heavy oxidation. It has been
used at the Mint for this function as a heavy oxide skin can cause sampling and
assaying problems.
Manganese Dioxide-is an effective oxidising agent, but more importantly has a
high affinity for sulphur and is in fact used extensively in desulphurising steels.
Hence if it is known that a concentrate has a high sulphide content, then
manganese dioxide as a fluxing agent is most beneficial.
Fluorspar- like Borax increases the fluidity of almost any slag. How it does this is
somewhat of a mystery, since its melting point of 1380 o C is above that normally
intended for precious metal smelting. Most authorities state that it is inert and
does not enter, to any extent, into combination with the other constituents of the
charge.